First you need to buy a serpentine tension release tool. A standard wrench will not work well. Once you have the tension released from the belt it will slip off of the pulleys. There is a diagram of the belt installation under the hood. Follow these instructions to install the new belt.How to change the serpentine belt on a 1997 buick skylark?
there should be a belt tensioner, you should be able to pull up on the belt and see it move, most of the time there will be a 3/8 square that you can put a ratchet in, push the direction that will release the tension, when installing the new belt i find it easier to put the belt over the alternator last because you'll have to do it while pushing the tensioner